Supramolecular architectures of neutral and cationic complexes of transition metals with lactate and 1,10-phenanthroline

被引：22

作者：

Covelo, Berta ^{[1
]}

Carballo, Rosa

Vázquez-López, Ezequiel M.

García-Martínez, Emilia

Castiñeiras, Alfonso

Balboa, Susana

Niclós, Juan

机构：

[1] Univ Vigo, Dept Quim Inorgan, Fac Quim, E-36310 Vigo, Spain

[2] Univ Santiago de Compostela, Fac Farm, Dept Quim Inorgan, E-15782 Santiago De Compostela, Spain

[3] Univ Granada, Fac Farm, Dept Quim Inorgan, E-18071 Granada, Spain

来源：

CRYSTENGCOMM | 2006年 / 8卷 / 02期

关键词：

D O I：

10.1039/b515539h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The following molecular complexes of transition metals M-II with lactato (HL) and 1,10-phenanthroline (phen) ligands were prepared and characterized structurally: [M(HL)(2)(phen)](nH2O)-H-., M-II = Mn, Co, Ni, Cu, Zn; 1 - 6), [M(HL)(H2O)(2)(phen)]Cl, (M-II = Mn, Co, Ni; 7 - 9), and [Ni(HL)(H2O)(2)(phen)]Br (10). These neutral and cationic octahedral complexes have 3-D supramolecular architectures due to weak noncovalent interactions. In the halide compounds, C - (HX-)-X-... hydrogen bonds play a key role in the stabilization of the 3-D network.

引用

页码：167 / 177

页数：11

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