The CA.M lattice revisited.: Gel formation from a linear bis-isocyanuric acid and 2-amino-4,6-bis-(4-tert-butylphenylamino)-1,3,5-triazine

被引:45
作者
Plater, MJ [1 ]
Sinclair, JP
Aiken, S
Gelbrich, T
Hursthouse, MB
机构
[1] Univ Aberdeen, Dept Chem, Meston Walk, Aberdeen AB24 3UE, Scotland
[2] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England
关键词
2-amino-4,6-bis-(4-tert-butylphenylamino)-1,3,5-triazine; cyanuric acid; hydrogen bonding; rosette motif;
D O I
10.1016/j.tet.2004.03.059
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Five bis(isocyanuric) acid dimers have been prepared and characterised. The introduction of flexible alkyl chains was necessary to aid solubility. On mixing with N,N-bis(4-tert-butyphenyl)melamine in THF followed by slow evaporation, a viscous gel can form which is interpreted as evidence for the assembly of an infinite 2-D hydrogen bonded network. (C) 2004 Published by Elsevier Ltd.
引用
收藏
页码:6385 / 6394
页数:10
相关论文
共 24 条
[1]   Novel type of hydrogen-bonded assemblies based on the melamine-cyanuric acid motif [J].
Arduini, M ;
Crego-Calama, M ;
Timmerman, P ;
Reinhoudt, DN .
JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (03) :1097-1106
[2]   Thermodynamic stabilities of linear and crinkled tapes and cyclic rosettes in melamine-cyanurate assemblies: A model description [J].
Bielejewska, AG ;
Marjo, CE ;
Prins, LJ ;
Timmerman, P ;
de Jong, F ;
Reinhoudt, DN .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (31) :7518-7533
[3]   Outlier treatment in data merging [J].
Blessing, RH .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1997, 30 :421-426
[4]   AN EMPIRICAL CORRECTION FOR ABSORPTION ANISOTROPY [J].
BLESSING, RH .
ACTA CRYSTALLOGRAPHICA SECTION A, 1995, 51 :33-38
[5]  
CARTER CW, MACROMOLECULAR CRY A, P307
[6]  
KANG SK, 2001, J CHEM SOC 1, V7, P736
[7]   Synthesis of a nonionic water soluble semiconductive polymer [J].
Kuroda, K ;
Swager, TM .
CHEMICAL COMMUNICATIONS, 2003, (01) :26-27
[8]   Syntheses and emission properties of novel violet-blue emissive aromatic bis(diazaborole)s [J].
Maruyama, S ;
Kawanishi, Y .
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (08) :2245-2249
[9]   SYNTHESIS OF ALKYL-SUBSTITUTED AND ALKOXY-SUBSTITUTED BENZILS AND OXIDATIVE COUPLING TO TETRAALKOXYPHENANTHRENE-9,10-DIONES [J].
MOHR, B ;
ENKELMANN, V ;
WEGNER, G .
JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (03) :635-638
[10]   Processing of X-ray diffraction data collected in oscillation mode [J].
Otwinowski, Z ;
Minor, W .
MACROMOLECULAR CRYSTALLOGRAPHY, PT A, 1997, 276 :307-326