Removal of copper-based catalyst in atom transfer radical polymerization using ion exchange resins

被引：143

作者：

Matyjaszewski, K ^{[1
]}

Pintauer, T ^{[1
]}

Gaynor, S ^{[1
]}

机构：

[1] Carnegie Mellon Univ, Dept Chem, Ctr Macromol Engn, Pittsburgh, PA 15213 USA

来源：

MACROMOLECULES | 2000年 / 33卷 / 04期

关键词：

D O I：

10.1021/ma9911445

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

An efficient method was established for the removal of Cu(I) and Cu(II) complexes in atom transfer radical polymerization (ATRP) using ion exchange resins with acidic groups. In the laboratories, these resins were used to remove copper catalysts from bulk, polymerization, and organic solutions. It was found that the rate of removal of copper complexes was dependent on the solvent polarity, temperature, type of ion exchange resins used, and ionic character and size of the copper complex.

引用

页码：1476 / 1478

页数：3

共 18 条

[1] DESIGN AND DEVELOPMENT OF POLYMER-BASED SEPARATIONS - DUAL MECHANISM BIFUNCTIONAL POLYMERS AS A NEW CATEGORY OF METAL-ION COMPLEXING AGENTS WITH ENHANCED IONIC RECOGNITION
ALEXANDRATOS, SD
[J]. SEPARATION AND PURIFICATION METHODS, 1988, 17 (01): : 67 - 102
[2] 5-COORDINATED HIGH-SPIN COMPLEXES OF BIVALENT COBALT NICKEL AND COPPER WITH TRIS(2-DIMETHYLAMINOETHYL)AMINE
CIAMPOLINI, M
NARDI, N
[J]. INORGANIC CHEMISTRY, 1966, 5 (01) : 41 - +
[3] THE ION-EXCHANGE EQUILIBRIUM
DEBOKX, PK
BOOTS, HMJ
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (25) : 8243 - 8248
[4] ADSORPTION STUDIES ON CLAY MINERALS .2. A FORMULATION OF THE THERMODYNAMICS OF EXCHANGE ADSORPTION
GAINES, GL
THOMAS, HC
[J]. JOURNAL OF CHEMICAL PHYSICS, 1953, 21 (04) : 714 - 718
[5] Controlled/"living" radical polymerization applied to water-borne systems
Gaynor, SG
Qiu, J
Matyjaszewski, K
[J]. MACROMOLECULES, 1998, 31 (17) : 5951 - 5954
[6] GAYNOR SG, 1998, ACS SYM SER, V685, P396
[7] A THEORETICAL TREATMENT OF CATION EXCHANGERS .1. THE PREDICTION OF EQUILIBRIUM CONSTANTS FROM OSMOTIC DATA
GLUECKAUF, E
[J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1952, 214 (1117): : 207 - 225
[8] A GENERAL THERMODYNAMIC THEORY OF ION EXCHANGE PROCESSES
GREGOR, HP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1948, 70 (03) : 1293 - 1293
[9] Atom transfer polymerisation of methyl methacrylate mediated by solid supported copper catalysts
Haddleton, DM
Kukulj, D
Radigue, AP
[J]. CHEMICAL COMMUNICATIONS, 1999, (01) : 99 - 100
[10] MODEL FOR ION-EXCHANGE RESINS
HARRIS, FE
RICE, SA
[J]. JOURNAL OF CHEMICAL PHYSICS, 1956, 24 (06) : 1258 - 1258

← 1 2 →