Reduction of nitric oxide with methane on Pd/Co/H-ZSM-5 catalysts: Cooperative effects of Pd and Co

被引:76
作者
Ogura, M [1 ]
Sugiura, Y [1 ]
Hayashi, M [1 ]
Kikuchi, E [1 ]
机构
[1] WASEDA UNIV,DEPT APPL CHEM,SHINJUKU KU,TOKYO 169,JAPAN
关键词
NO reduction; methane; palladium; cobalt; H-ZSM-5; zeolite; cooperative effect;
D O I
10.1007/BF00810686
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Reduction of low concentration of nitric oxide (NO) with methane as a reductant under wet conditions has been investigated using Pd/Co/H-ZSM-5 catalysts and the effects brought about by coexistence of Pd and Co are discussed. The role of Co is attributed to the acceleration of oxidation of NO to NO2, which is the necessary species for reduction of NO with CH4 on Pd sites. A Pd/H-ZSM-5 loading of 1 wt% Co shows a maximum activity for NO reduction as well as for NO oxidation. Excess loading of Co led to a decrease in activity for NO reduction. An XPS study shows that Pd and Co are well dispersed inside the zeolite when the concentrations of Pd and Co are less than 1 wt%. Loading of excess Co, however, causes aggregation of Pd on the surface of ZSM-5.
引用
收藏
页码:185 / 189
页数:5
相关论文
共 22 条
[1]  
Brandin JGM, 1989, CATAL TODAY, V4, P187
[2]   SELECTIVE REDUCTION OF NITRIC-OXIDE OVER CU/ZSM-5 - THE ROLE OF OXYGEN IN SUPPRESSING CATALYST DEACTIVATION BY CARBONACEOUS DEPOSITS [J].
DITRI, JL ;
SACHTLER, WMH .
APPLIED CATALYSIS B-ENVIRONMENTAL, 1993, 2 (2-3) :L7-L15
[3]   HIGHLY SELECTIVE REDUCTION OF NITROGEN-OXIDES WITH HYDROCARBONS OVER H-FORM ZEOLITE CATALYSTS IN OXYGEN-RICH ATMOSPHERES [J].
HAMADA, H ;
KINTAICHI, Y ;
SASAKI, M ;
ITO, T ;
TABATA, M .
APPLIED CATALYSIS, 1990, 64 (1-2) :L1-L4
[4]  
Held W., 1990, SAE T, P209
[5]  
Hirao Y., 1996, J CHEM SOC CHEM COMM, P597
[6]   Cooperative effect of platinum and alumina for the selective reduction of nitrogen monoxide with propane [J].
Inaba, M ;
Kintaichi, Y ;
Hamada, H .
CATALYSIS LETTERS, 1996, 36 (3-4) :223-227
[7]  
IWAMOTO M, 1990, JAN P M CAT TECHN RE, P17
[8]   Promotive effect of additives to In/H-ZSM-5 catalyst for selective reduction of nitric oxide with methane in the presence of water vapor [J].
Kikuchi, E ;
Ogura, M ;
Aratani, N ;
Sugiura, Y ;
Hiromoto, S ;
Yogo, K .
CATALYSIS TODAY, 1996, 27 (1-2) :35-40
[9]   SELECTIVE CATALYTIC REDUCTION OF NITROGEN MONOXIDE BY METHANE ON ZEOLITE CATALYSTS IN AN OXYGEN-RICH ATMOSPHERE [J].
KIKUCHI, E ;
YOGO, K .
CATALYSIS TODAY, 1994, 22 (01) :73-86
[10]  
KOBAYASHI W, 1993, Patent No. 208138