Synthesis and structural characterization of chiral amine alcohol complexes of aluminum

被引：40

作者：

Atwood, DA ^{[1
]}

Gabbai, FP ^{[1
]}

Lu, JL ^{[1
]}

Remington, MP ^{[1
]}

Rutherford, D ^{[1
]}

Sibi, MP ^{[1
]}

机构：

[1] TECH UNIV MUNICH,INST INORGAN & ANALYT CHEM,W-8046 GARCHING,GERMANY

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 09期

关键词：

D O I：

10.1021/om9509913

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses and full characterization of chiral amine alcohol complexes of aluminum are reported. These complexes are of two general formulae, those resulting from the reaction of 1 equiv of an aluminum reagent with an amine alcohol, [AA-AlR(2)](2) (where AA = phenylglycinol (PGly), R = Me (1), Et (2), SiMe(3) (3); phenylalaninol (PAla), R = Me (4), Et (5), SiMe(3) (6); and diphenylalaninol (DPAla), R = Me (7), Et (8), SiMe(3) (9), and the series resulting from the reaction of 2 equiv of AlMe(3) with an amine alcohol, AA(AlMe(2))-AlMe(3) (where AA = PGly (10), PAla (11), and DPAla (12)). These compounds significantly increase the number of chiral group 13 complexes that have been reported in the literature. Additionally, the crystal structures of 5, 6, and 11 have been obtained.

引用

页码：2308 / 2313

页数：6

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