A chlorinated phenazine-based donor-acceptor copolymer with enhanced photovoltaic performance

被引:34
作者
Li, Ying [1 ,2 ]
Meng, Bin [1 ,2 ]
Tong, Hui [1 ]
Xie, Zhiyuan [1 ]
Wang, Lixiang [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
基金
中国国家自然科学基金;
关键词
HETEROJUNCTION SOLAR-CELLS; BAND-GAP POLYMERS; CONJUGATED POLYMERS; RATIONAL DESIGN; FUNCTIONAL MATERIALS; DERIVATIVES; TRANSISTORS; MORPHOLOGY; CONVERSION;
D O I
10.1039/c3py01436c
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Chlorinated phenazine-based donor-acceptor conjugated copolymer PCTClP was designed and synthesized through Suzuki coupling polymerization. Compared to the unsubstituted copolymer PCTP, PCTClP exhibited a narrower band gap and a lower HOMO energy level. PCTClP/PC71BM based polymer solar cells show improved photovoltaic performance with power conversion efficiencies up to 4.06%.
引用
收藏
页码:1848 / 1851
页数:4
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