Factors controlling the electrical conductivity of ice from the polar regions - A summary

被引:51
作者
Wolff, EW [1 ]
Miners, WD [1 ]
Moore, JC [1 ]
Paren, JG [1 ]
机构
[1] UNIV LAPLAND,ARCTIC CTR,SF-96101 ROVANIEMI,FINLAND
来源
JOURNAL OF PHYSICAL CHEMISTRY B | 1997年 / 101卷 / 32期
关键词
D O I
10.1021/jp9631543
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Data on the relationship between the electrical conductivity and the chemistry of ice cores from the polar regions are summarized, The electrical conductivity measurement is used as a proxy for de conductivity, while dielectric profiling gives high-frequency conductivity. The de conductivity seems to be controlled entirely by the acidity of the ice, with a secondary effect of the accompanying anion. There is no positive response when huge excesses of sea salt, ammonium, or calcium are present, except in ice where brine is present. The high-frequency conductivity is controlled by acidity, ammonium, and chloride. This finding can be accommodated within Jaccard theory, but the relative response at high frequency to the three ions seems puzzling. The possibility that de conduction may be through grain boundaries can also not be discounted.
引用
收藏
页码:6090 / 6094
页数:5
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