A bis(ortho-amine)aryl-gold(I) compound as an efficient, nontoxic, arylating reagent

被引：80

作者：

Contel, M

Stol, M

Casado, MA

van Klink, GPM

Ellis, DD

Spek, AL

van Koten, G

机构：

[1] Univ Utrecht, Dept Met Mediated Synth, Debye Inst, NL-3584 CH Utrecht, Netherlands

[2] Univ Utrecht, Dept Crystal & Struct Chem, Bijvoet Ctr Biomol Res, NL-3584 CH Utrecht, Netherlands

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 21期

关键词：

D O I：

10.1021/om020286b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel strategy for the synthesis of bis(orthoamine)chelated monoanionic bisaminoaryl-metal complexes is presented. This method constitutes the exchange of a. monoanionic, NCN-pincer ligand (NCN = [C6H3(CH2-NMe2)(2)-2,6](-)) between a stable arylgold(I) phosphine, [Au(eta(1)-C-NCN)(PPh3)] (2), and a transition metal halide. This transmetalation results in the quantitative formation of[M(NCN)] organometallic compounds (M = Au-III, Ni-II Pd-II Pt-II, Ti-IV, and Fe-III) and [AuCl(PPh3)] as the only coproduct that can be recovered.

引用

页码：4556 / 4559

页数：4

共 37 条

[1] Transcyclometalation processes with late transition metals:: Caryl-H bond activation via noncovalent C-H•••interactions [J].