In situ Fourier transform infrared characterization of sulfur species resulting from the reaction of water vapor and oxygen with zinc sulfide

Steam is utilized as a diluent in the regeneration of zinc-based hot gas desulfurization sorbents used in fuel gas cleanup. Therefore, the effect of water vapor on the interaction of zinc sulfide (ZnS) with oxygen at 823, 873, and 923 K was studied using Fourier transform infrared (FTIR) spectroscopy. When ZnS at 823 K was exposed to oxygen, sulfate (SO42-) was the most prominent species observed at oxygen pressures greater than 5 x 10(-2) Torr while sulfite (SO32-) was the major species observed during the water vapor exposures. When ZnS at 823 K was exposed to an equimolar mixture of water vapor and oxygen, sulfite and sulfate were the most prominent products but the intensity of the sulfite peak was more than that of the sulfate. The sulfur species formed during the water vapor and oxygen exposures at both 873 and 923 K were similar to those at 823 K, but the relative intensities of the peaks corresponding to these sulfur species were different. At all three temperatures, the presence of water vapor enhanced the formation of sulfite, which can be decomposed more readily than sulfate. Thus, it is hypothesized that it would be desirable to have water vapor present during the regeneration of ZnS to form ZnO.