Chemoselective nucleophilic arylation and single-step oxidative esterification of aldehydes using siloxanes and a palladium-phosphinous acid as a reaction switch

被引：132

作者：

Lerebours, Rachel ^{[1
]}

Wolf, Christian ^{[1
]}

机构：

[1] Georgetown Univ, Dept Chem, Washington, DC 20057 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 40期

关键词：

D O I：

10.1021/ja063476c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aldehydes and siloxanes form methyl esters in a single step through mild oxidative esterification in the presence of a palladium catalyst or, alternatively, afford secondary alcohols via TBAF-promoted arylation in the absence of a catalyst at increased temperatures under otherwise identical reaction conditions. Copyright © 2006 American Chemical Society.

引用

页码：13052 / 13053

页数：2

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