Hybrid Silica-Polymer Ionogel Solid Electrolyte with Tunable Properties

被引：94

作者：

Guyomard-Lack, Aurelie ^{[1
]}

Abusleme, Julio ^{[2
]}

Soudan, Patrick ^{[1
]}

Lestriez, Bernard ^{[1
]}

Guyomard, Dominique ^{[1
]}

Le Bideau, Jean ^{[1
]}

机构：

[1] Univ Nantes, CNRS, Inst Mat Jean Rouxel, F-44322 Nantes 3, France

[2] Solvay Special Polymers, I-20021 Bollate, MI, Italy

来源：

ADVANCED ENERGY MATERIALS | 2014年 / 4卷 / 08期

关键词：

IONIC LIQUIDS; PVDF;

D O I：

10.1002/aenm.201301570

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

Solid and flexible ionogel-based membranes are obtained by a simple one-step process. Tuning the composition of the silica-polymer hybrid membranes allows the attainment of highly specific properties. The high ionic conductivities of the solid membranes are in the range of those of the ionic liquid electrolytes on which they are based. Good mechanical properties and high transparency from 250 to 1000 nm are also observed. The membranes are successfully applied within entirely solid lithium batteries. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

收藏

页数：5

相关论文

共 25 条

[1]

Nanomaterials for rechargeable lithium batteries [J].

Bruce, Peter G. ;

Scrosati, Bruno ;

Tarascon, Jean-Marie .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (16) :2930-2946

[2]

Biopolymer based nanocomposite ionogels: high performance, sustainable and solid electrolytes [J].

Buchtova, Nela ;

Guyomard-Lack, Aurelie ;

Le Bideau, Jean .

GREEN CHEMISTRY, 2014, 16 (03) :1149-1152

[3]

Ionic conductivity studies of gel polyelectrolyte based on ionic liquid [J].

Cha, E. H. ;

Lim, S. A. ;

Park, J. H. ;

Kim, D. W. ;

Macfarlane, D. R. .

JOURNAL OF POWER SOURCES, 2008, 178 (02) :779-782

[4]

Novel Ternary Composite Electrolytes: Li Ion Conducting Ionic Liquids in Silica Glass [J].

Echelmeyer, Thomas ;

Meyer, Hinrich Wilhelm ;

van Wuellen, Leo .

CHEMISTRY OF MATERIALS, 2009, 21 (11) :2280-2285

[5]

Lithium ion conducting PVdF-HFP composite gel electrolytes based on N-methoxyethyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)-imide ionic liquid [J].

Ferrari, S. ;

Quartarone, E. ;

Mustarelli, P. ;

Magistris, A. ;

Fagnoni, M. ;

Protti, S. ;

Gerbaldi, C. ;

Spinella, A. .

JOURNAL OF POWER SOURCES, 2010, 195 (02) :559-566

[6]

Unique Combination of Mechanical Strength, Thermal Stability, and High Ion Conduction in PMMA-Silica Nanocomposites Containing High Loadings of Ionic Liquid [J].

Gayet, Florence ;

Viau, Lydie ;

Leroux, Fabrice ;

Mabille, Frederic ;

Monge, Sophie ;

Robin, Jean-Jacques ;

Vioux, Andre .

CHEMISTRY OF MATERIALS, 2009, 21 (23) :5575-5577

[7]

Surprisingly high, bulk liquid-like mobility of silica-confined ionic liquids [J].

Goebel, Ronald ;

Hesemann, Peter ;

Weber, Jens ;

Moeller, Eleonore ;

Friedrich, Alwin ;

Beuermann, Sabine ;

Taubert, Andreas .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2009, 11 (19) :3653-3662

[8]

AN INTEGRATED INFRARED-SENSOR USING THE PYROELECTRIC POLYMER PVDF [J].

HAMMES, PCA ;

REGTIEN, PPL .

SENSORS AND ACTUATORS A-PHYSICAL, 1992, 32 (1-3) :396-402

[9]

Hardwick L. J., 2010, LAWRENCE BERKELEY NA

[10]

Morphology, crystalline structure, and properties of poly(vinylidene fluoride)/silica hybrid composites [J].

Kim, JW ;

Cho, WJ ;

Ha, CS .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2002, 40 (01) :19-30