Electroreductive coupling of organic halides in alcoholic solvents. An example: The electrosynthesis of biaryls catalysed by nickel-2,2' bipyridine complexes.

被引：37

作者：

Courtois, V ^{[1
]}

Barhdadi, R ^{[1
]}

Troupel, M ^{[1
]}

Perichon, J ^{[1
]}

机构：

[1] UNIV PARIS 12,CNRS,UMR28,LAB ELECTROCHIM CATALYSE & SYNTHESE ORGAN,F-94320 THIAIS,FRANCE

来源：

TETRAHEDRON | 1997年 / 53卷 / 34期

关键词：

alcoholic solvent; biaryl electrosynthesis; nickel-bipyridine catalysis;

D O I：

10.1016/S0040-4020(97)00744-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alcohols like methanol or ethanol are suitable solvents for achieving the electrosynthesis of biaryls from aryl halides according to a procedure which involves a catalysis by nickel-2,2'-bipyridine complexes. All electrolyses were carried out at constant current in an undivided cell fitted with an iron or duralumin sacrificial anode. (C) 1997 Elsevier Science Ltd.

引用

页码：11569 / 11576

页数：8

共 16 条

[1] MECHANISM OF NICKEL-CATALYZED ELECTRON-TRANSFER ACTIVATION OF AROMATIC HALIDES .1. BIPHENYL ELECTROSYNTHESIS FROM BROMOBENZENE [J].

AMATORE, C ;

JUTAND, A ;

MOTTIER, L .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1991, 306 (1-2) :125-140

[2]

CHAUSSARD J, 1990, SYNTHESIS-STUTTGART, P369

[3] COUPLING OF ARYL CHLORIDES BY NICKEL AND REDUCING METALS [J].

COLON, I ;

KELSEY, DR .

JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (14) :2627-2637

[4] Nickel-catalyzed direct electrochemical cross-coupling between aryl halides and activated alkyl halides [J].

Durandetti, M ;

Nedelec, JY ;

Perichon, J .

JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (05) :1748-1755

[5]

Durandetti M, 1996, NEW J CHEM, V20, P659

[6] ELECTROCATALYTIC COUPLING OF ARYL HALIDES WITH (1,2-BIS(DI-2-PROPYLPHOSPHINO)BENZENE)NICKEL(0) [J].

FOX, MA ;

CHANDLER, DA ;

LEE, CJ .

JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (10) :3246-3255

[7]

GASSMANN J, 1995, Z NATURFORSCH B, V50, P953

[8]

LITTLE RD, 1997, TOP CURR CHEM, V184, P1

[9]

Lund H., 1991, ORGANIC ELECTROCHEMI

[10] A ZEROVALENT NICKEL-2,2'-BIPYRIDINE COMPLEX - AN EFFICIENT CATALYST FOR ELECTROCHEMICAL HOMOCOUPLING OF ORTHO-SUBSTITUTED HALIDES AND THEIR HETEROCOUPLING WITH META-SUBSTITUTED AND PARA-SUBSTITUTED HALIDES [J].

MEYER, G ;

ROLLIN, Y ;

PERICHON, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 333 (02) :263-267

← 1 2 →