Structures and properties of gold(I) complexes of interest in biochemical applications

被引：64

作者：

Abdou, Harlan E. ^{[1
,2
]}

Mohamed, Ahmed A. ^{[1
,2
]}

Fackler, John P., Jr. ^{[1
,2
]}

Burini, Alfredo ^{[3
]}

Galassi, Rossana ^{[3
]}

Lopez-de-Luzuriaga, Jose M. ^{[4
]}

Elena Olmos, M. ^{[4
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

[2] Texas A&M Univ, Mol Struct & Bonding Lab, College Stn, TX 77842 USA

[3] Univ Camerino, Dipartimento Sci Chim, I-62032 Camerino, Italy

[4] Univ La Rioja, Dept Quim, UA CSIC, Grp Sintesis Quim La Rioja, E-26004 Logrono, Spain

来源：

COORDINATION CHEMISTRY REVIEWS | 2009年 / 253卷 / 11-12期

关键词：

Gold(I); Thiolates; Amidinates; Ylides; Carbeniates; Pyrazolates; Luminescence; Sensors; RAY CRYSTAL-STRUCTURES; VAPOCHROMIC BEHAVIOR; GOLD(I)-GOLD(I) INTERACTIONS; ENVIRONMENTAL SENSORS; INFRARED-SPECTROSCOPY; RHEUMATOID-ARTHRITIS; SOLID-STATE; LUMINESCENCE; DINUCLEAR; ACID;

D O I：

10.1016/j.ccr.2009.02.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学];

摘要：

Gold(I) compounds have several potential roles in biologically related chemistry. The relatively low toxicity of gold and its lability allows human consumption of drugs formed with this element. Trinuclear and tetranuclear clusters look particularly interesting because of the strong basicity of the gold(I) centers in these molecules. Future studies are expected to lead to interesting new bio-related observations. The ability of gold(I) compounds to interact with themselves aurophilically and with other heavy element ions has produced spectroscopic properties which are sensitive to volatile organic compounds (VOCs) and other molecular interactions. Thus bio-applicability for sensing toxic components appears reasonable. (c) 2009 Elsevier B.V. All rights reserved.

引用

页码：1661 / 1669

页数：9

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