Catalytic hydrodehalogenation of organic compounds

被引：55

作者：

Lunin, VV

Lokteva, ES

机构：

[1] Department of Chemistry, M. V. Lomonosov Moscow Stt. Univ., 119899 Moscow, Vorob'evy Gory

来源：

RUSSIAN CHEMICAL BULLETIN | 1996年 / 45卷 / 07期

关键词：

catalytic hydrodehalogenation; organohaloderivatives; freons; polychlorinated dioxines and biphenyls;

D O I：

10.1007/BF01431781

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Recent results on hydrodehalogenation (HDH) of alkyl halides, freons, aryl halides, polychlorinated derivatives of benzodioxines and biphenyls, and other compounds in the presence of heterogeneous and homogeneous catalysts are generalized. Effective and selective hydrodehalogenation proceeds via anion or radical anion intermediates. Special attention is given to the nature of the source of the hydrogen replacing the halogen.

引用

页码：1519 / 1534

页数：16

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