Optical ligand-to-ligand charge transfer of (1,2-diimine)Pt(II)(mu-S2MS2) with M = Mo(VI) and W(VI)

被引：8

作者：

Kunkely, H ^{[1
]}

Vogler, A ^{[1
]}

机构：

[1] UNIV REGENSBURG,INST ANORGAN CHEM,D-93040 REGENSBURG,GERMANY

来源：

INORGANICA CHIMICA ACTA | 1997年 / 264卷 / 1-2期

关键词：

charge transfer; platinum complexes; diimine complexes; tetrathiometallate complexes;

D O I：

10.1016/S0020-1693(97)05585-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The binuclear complexes Pt-II(1,2-diimine)(mu-(S2MS2)-S-VI) With 1,2-diimine = 2,2'-bipyridyl and biacetyl bis(anil) and M = Mo and W show long-wavelength absorption bands above 550 nm which are assigned to ligand-to-ligand charge transfer transitions from the bridging sulfide to the diimine ligands. (C) 1997 Elsevier Science S.A.

引用

页码：305 / 307

页数：3

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