Lipase catalyzed copolymerization of 3(S)-isopropylmorpholine-2,5-dione and D,L-lactide

被引：27

作者：

Feng, Y

Klee, D

Höcker, H

机构：

[1] Rhein Westfal TH Aachen, Lehrstuhl Text Chem & Makromol Chem, D-52062 Aachen, Germany

[2] Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China

来源：

MACROMOLECULAR BIOSCIENCE | 2004年 / 4卷 / 06期

关键词：

biodegradable; biomaterials; copolymerization; enzymes; ring-opening polymerization;

D O I：

10.1002/mabi.200300067

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The polymerization and copolymerization of 3(S)-isopropylmorpholine-2,5-dione (IPMD) and D,L-lactide (DLLA) were carried out in the presence of Porcine pancreatic lipase type II (PPL) as a catalyst at 100 degreesC for 168 h. Homopolymers and random copolymers of various compositions were obtained with a carboxylic acid group at one end and a hydroxyl group at the other end. The glass transition temperature of the copolymers decreases with increasing mole fraction of DLLA residue in the copolymers.

引用

页码：587 / 590

页数：4

共 30 条

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