A new synthetic route for preparing LiFePO4 with enhanced electrochemical performance

被引：190

作者：

Prosini, PP ^{[1
]}

Carewska, M

Scaccia, S

Wisniewski, P

Passerini, S

Pasquali, M

机构：

[1] ENEA, Adv Energy Technol, CR Casaccia, I-00060 Rome, Italy

[2] Univ Roma La Sapienza, Fac Ingn, Dipartimento ICMMPM, Rome, Italy

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2002年 / 149卷 / 07期

关键词：

D O I：

10.1149/1.1481716

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Nanocrystalline LiFePO4 was obtained by heating amorphous nanosized LiFePO4. The amorphous material was obtained by lithiation of FePO4 synthesized by spontaneous precipitation from equimolar aqueous solutions of Fe( NH4)(2) (SO4) (2).6H(2)O and NH4H2PO4, using hydrogen peroxide as the oxidizing agent. The materials were characterized by chemical analysis, thermogravimetric and differential thermal analysis, X-ray powder diffraction, and scanning electron microscopy. The Brunauer-Emmett-Teller method was used to evaluate the specific surface area. Nanocrystalline LiFePO4 showed very good electrochemical performance delivering about the full theoretical capacity (170 Ah kg(-1)) when cycled at the C/10 rate. A capacity fade of about 0.25% per cycle affected the material upon cycling. (C) 2002 The Electrochemical Society.

引用

页码：A886 / A890

页数：5

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