Evaluation of rate constant for electron transfer from C60-anion radical to molecular oxygen by laser flash photolysis method

被引:24
作者
Konishi, T [1 ]
Fujitsuka, M [1 ]
Ito, O [1 ]
机构
[1] Tohoku Univ, Inst Chem React Sci, Aoba Ku, Sendai, Miyagi 9808577, Japan
关键词
D O I
10.1246/cl.2000.202
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The rate constant for electron transfer from C-60-anion radical (C-60(.-)) to molecular oxygen was evaluated to be (3.7 +/- 0.2) x 10(2) mol(-1) dm(3) s(-1) in benzonitrile by following the concentration of the C-60(.-) by laser flash photolysis with a detector in the near-IR region for long time scale (> 0.1 s).
引用
收藏
页码:202 / 203
页数:2
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