The effects of battlefield contaminants on PEMFC performance

被引:153
作者
Moore, JM [1 ]
Adcock, PL
Lakeman, JB
Mepsted, GO
机构
[1] Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England
[2] Univ Loughborough, Dept Aeronaut & Automot Engn, Loughborough LE11 3TU, Leics, England
[3] Def Evaluat & Res Agcy, Gosport PO12 2AG, Hants, England
关键词
chemical warfare; battlefield contaminants; PEMFC; oxidant; fuel cell;
D O I
10.1016/S0378-7753(99)00341-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The effects of contaminants on the performance of an air breathing proton exchange membrane fuel cell (PEMFC) were investigated, by introduction into oxidant air fed to the fuel cell. The impact of the common pollutants sulphur dioxide, nitrogen dioxide, carbon monoxide, propane and benzene and the chemical warfare agents, sarin, sulphur mustard, cyanogen chloride (CNCl) and hydrogen cyanide (HCN) were assessed. At the concentrations studied, the common contaminants had either no effect on performance or caused a reversible depression. The chemical warfare agents all seriously compromised the performance of the fuel cells in an irreversible manner. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:254 / 260
页数:7
相关论文
共 9 条
[1]  
BOWER JS, 1994, AIR POLLUTION UK DEP
[2]   ELECTROCHEMICAL OXIDATION OF ADSORBED CARBON-MONOXIDE ON PLATINUM SPHERICAL SINGLE-CRYSTALS - EFFECT OF ANION ADSORPTION [J].
DEBECDELIEVRE, AM ;
DEBECDELIEVRE, J ;
CLAVILIER, J .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1990, 294 (1-2) :97-110
[3]   NATURE OF CO ADSORPTION DURING H-2 OXIDATION IN RELATION TO MODELING FOR CO POISONING OF A FUEL-CELL ANODE [J].
DHAR, HP ;
CHRISTNER, LG ;
KUSH, AK .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (12) :3021-3026
[4]   PERFORMANCE STUDY OF A FUEL-CELL PT-ON-C ANODE IN PRESENCE OF CO AND CO2, AND CALCULATION OF ADSORPTION PARAMETERS FOR CO POISONING [J].
DHAR, HP ;
CHRISTNER, LG ;
KUSH, AK ;
MARU, HC .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1986, 133 (08) :1574-1582
[5]   A NEW APPROACH TO THE PROBLEM OF CARBON-MONOXIDE POISONING IN FUEL-CELLS OPERATING AT LOW-TEMPERATURES [J].
GOTTESFELD, S ;
PAFFORD, J .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1988, 135 (10) :2651-2652
[6]  
PINO L, 1998, FUEL CELL SEM, P671
[7]   INTERACTIONS AND DYNAMICS OF BENZENE ON CU(111) AT LOW-TEMPERATURE [J].
STRANICK, SJ ;
KAMNA, MM ;
WEISS, PS .
SURFACE SCIENCE, 1995, 338 (1-3) :41-59
[8]  
VELDIUS JBJ, 1998, FUEL CELL SEM, P598
[9]  
EXAMINATION ACTIVATE