A semi-molten mixture of hexadecyltributylphosphonium bromide and potassium fluoride in the synthesis of organofluorine compounds

被引：5

作者：

Bhadury, PS ^{[1
]}

Raza, SK ^{[1
]}

Jaiswal, DK ^{[1
]}

机构：

[1] Def Res & Dev Estab, Synthet Chem Div, Gwalior 474002, India

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1999年 / 99卷 / 02期

关键词：

semi-molten mixture hexadecyltributylphosphonium bromide; organofluorine compounds;

D O I：

10.1016/S0022-1139(99)00121-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A facile and effective reagent system comprising of a semi-molten mixture of hexadecyltributylphosphonium bromide and potassium fluoride has been developed and its scope has been investigated in nucleophilic fluoride exchange with various organohalides. This simple and convenient reagent system provides organofluorine compounds in high yields even with haloesters in which fluoride catalysed elimination is also feasible. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：115 / 117

页数：3

共 9 条

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