Two-photon absorption in azoaromatic compounds

被引:51
作者
De Boni, L [1 ]
Rodrigues, JJ [1 ]
dos Santos, DS [1 ]
Silva, CHTP [1 ]
Balogh, DT [1 ]
Oliveira, ON [1 ]
Zilio, SC [1 ]
Misoguti, L [1 ]
Mendonça, CR [1 ]
机构
[1] Inst Fis Sao Carlos, Dept Fis & Ciencia Mat, BR-13560970 Sao Carlos, SP, Brazil
基金
巴西圣保罗研究基金会;
关键词
D O I
10.1016/S0009-2614(02)00892-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report on the two-photon absorption (2PA) cross-section for eight azoaromatic compounds in dimethyl sulfoxide solutions, using the Z-scan technique with femtosecond laser pulses at 775 nm. The 2PA cross-sections of these molecules are of the order of (1-6) x 10(-50) cm(4) s photon(-1). A correlation was established between the molecular structure and the two-photon absorption process, which makes it possible to develop molecular design strategies to create structures with suitable two-photon absorption coefficients. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:209 / 213
页数:5
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