Selective synthesis and characterization of CdSe nanorods and fractal nanocrystals

被引：174

作者：

Peng, Q ^{[1
]}

Dong, YJ ^{[1
]}

Deng, ZX ^{[1
]}

Li, YD ^{[1
]}

机构：

[1] Tsinghua Univ, Minist Educ, Key Lab Atom & Mol Nanosci, Dept Chem, Beijing 100084, Peoples R China

来源：

INORGANIC CHEMISTRY | 2002年 / 41卷 / 20期

关键词：

D O I：

10.1021/ic0257266

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

CdSe nanorods and dendritic fractals were synthesized through a novel controllable solution-phase hydrothermal method. Soluble selenite was employed to provide a highly reactive Se source in the synthesis. Both morphologies and phases of the CdSe products could be successfully controlled by choosing appropriate complexing agents to adjust the dynamics of the reaction process. Reaction temperature and Cd/Se ratio in raw materials were also important parameters influencing the morphologies and phases of the products. The phase structures, morphologies, and optical properties of the CdSe products were investigated by XRD, TEM, HRTEM, and UV-vis and photoluminescence spectroscopies. The formation mechanisms of the nanorods and fractals were investigated and discussed on the basis of the experimental results.

引用

页码：5249 / 5254

页数：6

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