Activation of a non-strained C-C bond with platinum(II)

被引：42

作者：

vanderBoom, ME ^{[1
]}

Kraatz, HB ^{[1
]}

BenDavid, Y ^{[1
]}

Milstein, D ^{[1
]}

机构：

[1] WEIZMANN INST SCI,DEPT ORGAN CHEM,IL-76100 REHOVOT,ISRAEL

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 18期

关键词：

D O I：

10.1039/cc9960002167

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The aromatic phosphine 1 reacts with (cod)PtCl2 to yield the C-H activation product 2; treatment of 2 with HCl results in overall selective functionalization of the strong Ar-Me bond to generate MeCl and the Ar-Pt complex 3.

引用

页码：2167 / 2168

页数：2

共 27 条

[1] NUCLEAR MAGNETIC RESONANCE SPECTRA OF SOME PHOSPHINE COMPLEXES OF PLATINUM ALKYLS AND ARYLS [J].

ALLEN, FH ;

PIDCOCK, A .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (11) :2700-&

[2] PREPARATION AND X-RAY STRUCTURE OF A PLATINUM(II) HYDROXYCARBONYL, PT(CO2H)(C6H3(CH2PPH2)2-2,6), CONTAINING A TRANS-SPANNING, TRIDENTATE P,C,P-LIGAND [J].

BENNETT, MA ;

JIN, H ;

WILLIS, AC .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 451 (1-2) :249-256

[3] INTERMOLECULAR ACTIVATION OF C-D BONDS IN BENZENE-D6 BY TRANS-NEOPENTYL(TRIFLUOROMETHANESULFONATO)BIS(TRIMETHYL-PHOSPHINE)PLATINUM(II) [J].

BRAINARD, RL ;

NUTT, WR ;

LEE, TR ;

WHITESIDES, GM .

ORGANOMETALLICS, 1988, 7 (11) :2379-2386

[4] MECHANISMS OF D(8) ORGANOMETALLIC REACTIONS INVOLVING ELECTROPHILES AND INTRAMOLECULAR ASSISTANCE BY NUCLEOPHILES [J].

CANTY, AJ ;

VANKOTEN, G .

ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (10) :406-413

[5] THE ORGANOMETALLIC CHEMISTRY OF ALKANES [J].

CRABTREE, RH .

CHEMICAL REVIEWS, 1985, 85 (04) :245-269

[6] MECHANISM OF THERMAL-DECOMPOSITION OF DINEOPENTYLBIS(TRIETHYLPHOSPHINE)PLATINUM(II) - FORMATION OF BIS(TRIETHYLPHOSPHINE)-3,3-DIMETHYLPLATINACYCLOBUTANE [J].

FOLEY, P ;

DICOSIMO, R ;

WHITESIDES, GM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (22) :6713-6725

[7] TRANSFER OF METHYLENE GROUPS PROMOTED BY METAL COMPLEXATION [J].

GOZIN, M ;

AIZENBERG, M ;

LIOU, SY ;

WEISMAN, A ;

BENDAVID, Y ;

MILSTEIN, D .

NATURE, 1994, 370 (6484) :42-44

[8] ACTIVATION OF A CARBON-CARBON BOND IN SOLUTION BY TRANSITION-METAL INSERTION [J].

GOZIN, M ;

WEISMAN, A ;

BENDAVID, Y ;

MILSTEIN, D .

NATURE, 1993, 364 (6439) :699-701

[9] REGIOSPECIFIC AND STEREOSPECIFIC NUCLEOPHILIC ADDITIONS TO A METAL-SUBSTITUTED CARBONIUM-ION, [PTI(MEC6H3(CH2NME2)2-0,0')]BF4 - A UNIQUE REVERSIBLE ARYL TO CYCLOHEXADIENE CONVERSION AT A PLATINUM(II) CENTER [J].

GROVE, DM ;

VANKOTEN, G ;

UBBELS, HJC .

ORGANOMETALLICS, 1982, 1 (10) :1366-1370

[10] TRANS 2,6-BIS[(DIMETHYLAMINO)METHYL]PHENYL-N,N',C COMPLEXES OF PD(II) AND PT(II) - CRYSTAL-STRUCTURE OF [PTI(MEC6H3(CH2NME2)2-O,O')]BF4 - A CYCLOHEXADIENYL CARBONIUM-ION WITH A SIGMA-BONDED METAL SUBSTITUENT [J].

GROVE, DM ;

VANKOTEN, G ;

LOUWEN, JN ;

NOLTES, JG ;

SPEK, AL ;

UBBELS, HJC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (24) :6609-6616

← 1 2 3 →