A novel two-dimensional structure containing the first antimony-substituted polyoxovandium clusters:: [{Co(en)2}2SbIII8VIV 14O42(H2O)]•6H2O

被引：81

作者：

Zhang, LJ ^{[1
]}

Zhao, XL ^{[1
]}

Xu, JQ ^{[1
]}

Wang, TG ^{[1
]}

机构：

[1] Jilin Univ, State Key Lab Inorgan Synthesis & Preparat Chem, Changchun 130023, Peoples R China

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 17期

关键词：

D O I：

10.1039/b206250j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The novel framework [{Co(en)(2)}(2)(Sb8V14O42)-V-III-O-IV (H2O)].6H(2)O is composed of two-dimensional arrays of {(Sb8V14O42)-V-III-O-IV (H2O)} clusters interlinked via {Co(en)(2)} bridging groups; such antimony-vanadium clusters with antimony and vanadium in low oxidation states were previously unknown.

引用

页码：3275 / 3276

页数：2

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