Multilayer sequential assembly of thin films that display room-temperature spin crossover with hysteresis

被引:268
作者
Cobo, Saioa
Molnar, Gabor
Real, Jose Antonio
Bousseksou, Azzedine
机构
[1] CNRS, Chim Coordinat Lab, UPR8241, F-31077 Toulouse, France
[2] Univ Valencia, Inst Ciencia Mol, Dept Quim Inorgan, Valencia 46071, Spain
关键词
coordination polymers; multilayer assemblies; Raman microscopy; spin crossover; thin films;
D O I
10.1002/anie.200601885
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Chemical Equation Presented) Assembly time: Thin films of [Fe(pyrazine){M(CN)4}] (M = Ni, Pd, or Pt) coordination polymers were assembled sequentially through coordinate bonding on gold surfaces (see scheme). These multilayers exhibit spin-crossover phenomena with hysteresis at room temperature. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:5786 / 5789
页数:4
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