Orbital ordering transition in La4Ru2O10

被引:97
作者
Khalifah, P
Osborn, R
Huang, Q
Zandbergen, HW
Jin, R
Liu, Y
Mandrus, D
Cava, RJ
机构
[1] Princeton Univ, Dept Chem, Princeton, NJ 08540 USA
[2] Princeton Univ, Princeton Mat Inst, Princeton, NJ 08540 USA
[3] Argonne Natl Lab, Div Sci Mat, Argonne, IL 60439 USA
[4] NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA
[5] Univ Maryland, Dept Mat & Nucl Engn, College Pk, MD 20742 USA
[6] Delft Univ Technol, Natl Ctr High Resolut Electron Microscopy, NL-2628 AL Delft, Netherlands
[7] Penn State Univ, Dept Phys, University Pk, PA 16802 USA
[8] Oak Ridge Natl Lab, Div Solid State, Oak Ridge, TN 37831 USA
关键词
D O I
10.1126/science.1075556
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
We report experimental evidence for a full orbital ordering transition in the two-dimensional lanthanum ruthenate La4Ru2O10. The observable consequences of this orbital ordering include the loss of the Ru local moment, a structural distortion which partitions Ru-O bonds into axially oriented short and long sets, a sharp jump in electrical resistivity, and the opening of a spin gap that is visible in neutron scattering experiments. This is a rare example of a discrete orbital ordering transition in a 4d transition metal oxide and demonstrates that orbital effects can have an influence on the properties of layered ruthenates, a family of compounds that notably includes the p-wave superconductor Sr2RuO4 and the field-tuned quantum critical metamagnet Sr3Ru2O7.
引用
收藏
页码:2237 / 2240
页数:5
相关论文
共 16 条
[1]   Orbital-selective Mott-insulator transition in Ca2-xSrxRuO4 [J].
Anisimov, VI ;
Nekrasov, IA ;
Kondakov, DE ;
Rice, TM ;
Sigrist, M .
EUROPEAN PHYSICAL JOURNAL B, 2002, 25 (02) :191-201
[2]   Transition between orbital orderings in YVO3 -: art. no. 245501 [J].
Blake, GR ;
Palstra, TTM ;
Ren, Y ;
Nugroho, AA ;
Menovsky, AA .
PHYSICAL REVIEW LETTERS, 2001, 87 (24) :245501-1
[3]   Crystal and magnetic structure of Ca2RuO4:: Magnetoelastic coupling and the metal-insulator transition [J].
Braden, M ;
Andre, G ;
Nakatsuji, S ;
Maeno, Y .
PHYSICAL REVIEW B, 1998, 58 (02) :847-861
[4]   Fermi surface nesting and nanoscale fluctuating charge/orbital ordering in colossal magnetoresistive oxides [J].
Chuang, YD ;
Gromko, AD ;
Dessau, DS ;
Kimura, T ;
Tokura, Y .
SCIENCE, 2001, 292 (5521) :1509-1513
[5]   Magnetic phase diagram of Ca2-xSrxRuO4 governed by structural distortions -: art. no. 020509 [J].
Fang, Z ;
Terakura, K .
PHYSICAL REVIEW B, 2001, 64 (02)
[6]  
FRIEDT O, 1998, PHYS REV B, V58, P847
[7]   Magnetoresistance in layered manganite compounds [J].
Goldman, AM .
SCIENCE, 1996, 274 (5293) :1630-1631
[8]   Prediction of orbital ordering in single-layered ruthenates [J].
Hotta, T ;
Dagotto, E .
PHYSICAL REVIEW LETTERS, 2002, 88 (01) :4-172014
[9]   Direct observation of orbital ordering in YTiO3 [J].
Ichikawa, H ;
Akimitsu, J ;
Nishi, M ;
Kakurai, K .
PHYSICA B, 2000, 281 :482-484
[10]   Metal-insulator transitions [J].
Imada, M ;
Fujimori, A ;
Tokura, Y .
REVIEWS OF MODERN PHYSICS, 1998, 70 (04) :1039-1263