Origin of deterioration for LiNiO2 cathode material during storage in air

被引：271

作者：

Liu, HS ^{[1
]}

Zhang, ZR

Gong, ZL

Yang, Y

机构：

[1] Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China

[2] Xiamen Univ, Dept Chem, Xiamen 361005, Peoples R China

来源：

ELECTROCHEMICAL AND SOLID STATE LETTERS | 2004年 / 7卷 / 07期

关键词：

D O I：

10.1149/1.1738471

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Lithium nickel oxide, a potential candidate for cathode material for lithium-ion batteries, showed a distinct deterioration after storage in air for a time. The origin of this deterioration was explored by investigating surface structure, surface species, and ionic oxidation state of fresh and stored LiNiO2 materials. Rietveld analysis of X-ray diffraction patterns showed not only the formation of Li2CO3 on the surface, but also a weakening of ordered layered structure for the stored materials. X-ray photoelectron spectroscopy revealed that Ni3+ transforms to Ni2+ and active oxygen species exist on the surface of stored materials. Temperature programmed desorption-mass spectroscopy measurements gave evidence that active oxygen species (O-, O-2(-)) occur on the surface of LiNiO2 after storage. A surface reaction mechanism based on the transformation of Ni3+/Ni2+ and the evolution of active oxygen species is proposed. (C) 2004 The Electrochemical Society.

引用

页码：A190 / A193

页数：4

共 15 条

[1] Thermal, electrochemical and structural properties of stabilized LiNiyCo1-y-zMzO2 lithium-ion cathode material prepared by a chemical route [J].

D'Epifanio, A ;

Croce, F ;

Ronci, F ;

Albertini, VR ;

Traversa, E ;

Scrosati, B .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2001, 3 (19) :4399-4403

[2] An overview of the Li(Ni,M)O2 systems:: syntheses, structures and properties [J].

Delmas, C ;

Ménétrier, M ;

Croguennec, L ;

Saadoune, I ;

Rougier, A ;

Pouillerie, C ;

Prado, G ;

Grüne, M ;

Fournès, L .

ELECTROCHIMICA ACTA, 1999, 45 (1-2) :243-253

[3] Formation and electronic properties of oxide and sulphide films of Co, Ni and Mo studied by XPS [J].

Galtayries, A ;

Grimblot, J .

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1999, 98 :267-275

[4]

Gao YA, 1998, ELECTROCHEM SOLID ST, V1, P117, DOI 10.1149/1.1390656

[5] Electronic state of nickel in barium nickel oxide, BaNiO3 [J].

Gottschall, R ;

Schollhorn, R ;

Muhler, M ;

Jansen, N ;

Walcher, D ;

Gutlich, P .

INORGANIC CHEMISTRY, 1998, 37 (07) :1513-1518

[6] STUDY OF METAL-OXIDE CATALYSTS BY TEMPERATURE PROGRAMMED DESORPTION .1. CHEMISORPTION OF OXYGEN ON NICKEL-OXIDE [J].

IWAMOTO, M ;

YODA, Y ;

EGASHIRA, M ;

SEIYAMA, T .

JOURNAL OF PHYSICAL CHEMISTRY, 1976, 80 (18) :1989-1994

[7]

LARSON AC, MSH805 LANSCE LOS AL

[8] The effects of sintering temperature and time on the structure and electrochemical performance of LiNi0.8Co0.2O2 cathode materials derived from sol-gel method [J].

Liu, HS ;

Li, J ;

Zhang, ZR ;

Gong, ZL ;

Yang, Y .

JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2003, 7 (08) :456-462

[9] Structural, electrochemical and thermal properties of LiNi0.8-yTiyCo0.2O2 as cathode materials for lithium ion battery [J].

Liu, HS ;

Li, J ;

Zhang, ZR ;

Gong, ZL ;

Yang, Y .

ELECTROCHIMICA ACTA, 2004, 49 (07) :1151-1159

[10] Effects of CO2 in air on Li deintercalation from LiNi1-x-yCoxAlyO2 [J].

Matsumoto, K ;

Kuzuo, R ;

Takeya, K ;

Yamanaka, A .

JOURNAL OF POWER SOURCES, 1999, 81 :558-561

← 1 2 →