The chiral S-N axis in sulfenamides: Enantiomeric resolution, direct demonstration of optical activity, and kinetics of interconversion

被引：19

作者：

Blanca, MBD ^{[1
]}

Maimon, E ^{[1
]}

Kost, D ^{[1
]}

机构：

[1] BEN GURION UNIV NEGEV,DEPT CHEM,IL-84105 BEER SHEVA,ISRAEL

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1997年 / 36卷 / 20期

关键词：

chirality; enantiomeric resolution; NMR spectroscopy; restricted rotation; sulfenamides;

D O I：

10.1002/anie.199722161

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[No abstract available]

引用

页码：2216 / 2219

页数：4

共 18 条

[1]

ATKINSON RS, 1978, TETRAHEDRON LETT, P3137

[2] THE PREPARATION OF TETRAHYDROCARBAZOLES FROM 2-CHLOROCYCLOHEXANONE [J].

CAMPBELL, N ;

MCCALL, EB .

JOURNAL OF THE CHEMICAL SOCIETY, 1950, (OCT) :2870-2874

[3] THE CHEMISTRY OF SULFENAMIDES [J].

CRAINE, L ;

RABAN, M .

CHEMICAL REVIEWS, 1989, 89 (04) :689-712

[4]

ELIEL EL, 1994, STEREOCHEMISTRY ORGA, P53

[5]

Helmchen G., 1982, ANGEW CHEM, V94, P614

[6] VALIDITY OF APPROXIMATE EQUATIONS FOR KC IN DYNAMIC NUCLEAR MAGNETIC RESONANCE [J].

KOST, D ;

CARLSON, EH ;

RABAN, M .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1971, (13) :656-&

[7]

KOST D, 1990, CHEM SULPHENIC ACIDS, P23

[8] THE CHEMISTRY OF CARBAZOLES .7. SYNTHESES OF METHYLCARBAZOLES [J].

KUROKI, M ;

TSUNASHIMA, Y .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1981, 18 (04) :709-714

[9] STEREOISOMERISM AND LOCAL CHIRALITY [J].

MISLOW, K ;

SIEGEL, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (11) :3319-3328

[10] SYNTHETIC METHODS AND REACTIONS .123. PREPARATION OF ALPHA-CHLORO KETONES FROM ENOL SILYL ETHERS WITH SULFURYL CHLORIDE FLUORIDE AND SULFURYL CHLORIDE [J].

OLAH, GA ;

OHANNESIAN, L ;

ARVANAGHI, M ;

PRAKASH, GKS .

JOURNAL OF ORGANIC CHEMISTRY, 1984, 49 (11) :2032-2034

← 1 2 →