A chiral dumbbell shaped bis(fullerene) oligoelectrolyte

被引：12

作者：

Chronakis, Nikos

Hartnagel, Uwe

Braun, Martin

Hirsch, Andreas

机构：

[1] Univ Cyprus, Dept Chem, CY-1678 Nicosia, Cyprus

[2] Univ Erlangen Nurnberg, Inst Organ Chem, D-91054 Erlangen, Germany

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 06期

关键词：

D O I：

10.1039/b614005j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first icosacationic bis(fullerene) whose water solubility is provided by twenty peripheral ammonium groups has a rigid, almost cylindrical shape and was synthesized by connecting two fullerene cores with a chiral cyclo-bis(malonate), followed by the regioselective addition of ten amino-terminated malonates into the octahedral positions of the fullerene moieties and subsequent cleavage of the Boc-protecting groups.

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页码：607 / 609

页数：3

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