Activation of nitrous oxide and selective oxidation of alcohols and alkylarenes catalyzed by the [PV2Mo10O40]5- polyoxometalate ion

被引：67

作者：

Ben-Daniel, R ^{[1
]}

Neumann, R ^{[1
]}

机构：

[1] Weizmann Inst Sci, Dept Organ Chem, IL-76100 Rehovot, Israel

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 01期

关键词：

alcohols; homogeneous catalysis; nitrogen oxides; oxidation; polyoxometalates;

D O I：

10.1002/anie.200390062

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A vanadium-substituted polyoxomolybdate ion ([PV2Mo10O40]5-, top right) can activate nitrous oxide to promote the highly selective catalytic oxidation of primary and secondary alcohols to aldehydes and ketones, and the oxidation of various alkylaromatic substrates (see scheme).

引用

页码：92 / 95

页数：4

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