Melamine-formaldehyde-NTA chelating gel resin: Synthesis, characterization and application for copper(II) ion removal from synthetic wastewater

被引:84
作者
Baraka, Ahmad [1 ]
Hall, P. J. [1 ]
Heslop, M. J. [1 ]
机构
[1] Univ Strathclyde, Dept Chem & Proc Engn, Glasgow G1 1XJ, Lanark, Scotland
关键词
melamine-formaldehyde-NTA resin; chelating adsorption; copper(II);
D O I
10.1016/j.jhazmat.2006.06.051
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A new chelating resin was synthesised by anchoring nitrilotriacetic acid (NTA) to melamine during the melamine-formaldehyde gelling reaction in the presence of water, using acetone and guaiacol as a porogen mixture. This technique gives a porous chelating gel resin capable of removing heavy metals from wastewater. FT-IR, XRD, elemental analysis, surface area and water regain measurements were conducted for characterization of the new chelating gel resin. A comprehensive adsorption study (kinetics isotherm, and thermodynamics) of Cu(II) removal from synthetic acidic aqueous solutions by adsorption on this resin was conducted regarding the effects of time, temperature, initial pH and copper(II) initial concentration. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:86 / 94
页数:9
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