Nanoscopic photoluminescence memory as a fingerprint of complexity in self-assembled alkyl/siloxane hybrids

被引：79

作者：

Carlos, Luis D. ^{[1
]}

Bermudez, Veronica de Zea

Amaral, Vitor S.

Nunes, Silvia C.

Silva, Nuno J. O.

Ferreira, Rute A. Sa

Rocha, Joao

Santilli, Celso V.

Ostrovskii, Denis

机构：

[1] Univ Aveiro, Dept Fis, P-3810193 Aveiro, Portugal

[2] Univ Aveiro, CICECO, P-3810193 Aveiro, Portugal

[3] Univ Tras Os Montes & Alto Douro, Dept Quim, P-500801 Vila Real, Portugal

[4] Univ Tras Os Montes & Alto Douro, CQ VR, P-500801 Vila Real, Portugal

[5] Univ Aveiro, Dept Quim, P-3810193 Aveiro, Portugal

[6] UNESP, Inst Quim, BR-14800900 Araraquara, SP, Brazil

[7] Chalmers, Dept Appl Phys, S-41296 Gothenburg, Sweden

来源：

ADVANCED MATERIALS | 2007年 / 19卷 / 03期

关键词：

D O I：

10.1002/adma.200601435

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A thermally activated photoluminescence memory effect, induced by a reversible order-disorder phase transition of the alkyl chains, is reported for highly organized bilayer alkyl/siloxane hybrids (see figure; left at room temperature, right at 120 degrees C). The emission energy is sensitive to the annihilation/formation of the hydrogen-bonded amide-amide array displaying a unique nanoscopic sensitivity (ca. 150 nm).

引用

页码：341 / +

页数：9

共 41 条

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