Deiodination of iodolactones by transfer hydrogenolysis using Raney nickel and 2-propanol

被引：9

作者：

Mebane, RC ^{[1
]}

Grimes, KD ^{[1
]}

Jenkins, SR ^{[1
]}

Deardorff, JD ^{[1
]}

Gross, BH ^{[1
]}

机构：

[1] Univ Tennessee, Dept Chem, Chattanooga, TN 37403 USA

来源：

SYNTHETIC COMMUNICATIONS | 2002年 / 32卷 / 13期

关键词：

catalytic transfer hydrogenolysis; deiodination; Raney nickel; iodolactone; lactone;

D O I：

10.1081/SCC-120004856

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Raney nickel in refluxing 2-propanol is an effective catalytic system for reducing iodolactones into their corresponding lactones.

引用

页码：2049 / 2054

页数：6

共 33 条

[1]

ANDREWS MJ, 1978, INDIAN J CHEM B, V16, P465

[2]

Augustine R.L., 1996, HETEROGENEOUS CATALY

[3] HETEROGENEOUS CATALYTIC TRANSFER HYDROGENATION OF 4-NITRODIPHENYLAMINE TO PARA-PHENYLENEDIAMINES [J].

BANERJEE, AA ;

MUKESH, D .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (18) :1275-1276

[4] Microwave-induced organic reaction enhancement (MORE) chemistry. Part 13. Microwave-assisted rapid and simplified hydrogenation [J].

Banik, BK ;

Barakat, KJ ;

Wagle, DR ;

Manhas, MS ;

Bose, AK .

JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (16) :5746-5753

[5] CATALYTIC TRANSFER HYDROGENATION [J].

BRIEGER, G ;

NESTRICK, TJ .

CHEMICAL REVIEWS, 1974, 74 (05) :567-580

[6] A SPIRO-ANNULATION APPROACH TO THE ZIZAANE SESQUITERPENES [J].

BURNELL, DJ ;

WU, YJ .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1990, 68 (06) :804-811

[7] ORGANOSILANES AS RADICAL-BASED REDUCING AGENTS IN SYNTHESIS [J].

CHATGILIALOGLU, C .

ACCOUNTS OF CHEMICAL RESEARCH, 1992, 25 (04) :188-194

[8] A NEW ENTRY TO HIGHLY FUNCTIONALIZED PERHYDROINDANS VIA FREE-RADICAL CYCLIZATIONS [J].

CHUANG, CP ;

HART, DJ .

JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (10) :1782-1784

[9] ATOM TRANSFER CYCLIZATION REACTIONS OF ALPHA-IODO ESTERS, KETONES, AND MALONATES - EXAMPLES OF SELECTIVE 5-EXO, 6-ENDO, 6-EXO, AND 7-ENDO RING CLOSURES [J].

CURRAN, DP ;

CHANG, CT .

JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (13) :3140-3157

[10]

DENTON DA, 1964, J CHEM SOC, VS, P5535

← 1 2 3 4 →