The preferred conformation of α-fluoroamides

被引：75

作者：

Banks, JW

Batsanov, AS

Howard, JAK

O'Hagan, D

Rzepa, HS

Martin-Santamaria, S

机构：

[1] GD Searle & Co, Dept Chem Technol, Morpeth NE61 3YA, England

[2] Univ Durham, Dept Chem, Sci Labs, Durham DH1 3LE, England

[3] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1999年 / 11期

关键词：

D O I：

10.1039/a907452j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

X-Ray structures of two alpha-fluoroamide derivatives show the O=C-C-F moiety tending towards a trans planar conformation, for which ab initio calculations suggest a deep (up to 8 kcal mol(-1)) potential minimum.

引用

页码：2409 / 2411

页数：3

共 18 条

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