Application of FT-IR spectroscopy to the characterisation and classification of wines, brandies and other distilled drinks

FT-IR spectra were employed for the differentiation and classification of wines and brandies during their ageing process, as well as for the characterisation and differentiation of distilled drinks from several producing countries. The FT-IR spectra have enabled the differentiation of the six scales of ageing of sherry wine. A good linear regression fit (regression coefficient = 0.995) has been obtained between ageing scale and the data of the FT-IR spectrum. In the case of Brandy of Jerez, it has been possible to differentiate the three degrees of ageing and to devise a system of classification by means of linear discriminant analysis, with a reliability of 83%. The application of the regression by partial least squares has allowed us to obtain a regression between the degree of ageing and the data of the FT-IR spectrum (correlation coefficient = 0.986). Lastly, Spanish, French and South African brandies, as well as cognacs and armagnacs have been characterised, and a complete differentiation of the latter two types from the rest of the samples of distilled drinks has been obtained. (C) 2002 Elsevier Science B.V. All rights reserved.