Semiempirical time-dependent unrestricted Hartree-Fock approach for the determination of molecular linear and nonlinear optical properties

被引：8

作者：

Botek, E ^{[1
]}

Champagne, B ^{[1
]}

机构：

[1] Fac Univ Notre Dame Paix, Lab Chim Theor Appl, B-5000 Namur, Belgium

来源：

CHEMICAL PHYSICS LETTERS | 2004年 / 387卷 / 1-3期

关键词：

D O I：

10.1016/j.cplett.2004.02.004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The time-dependent unrestricted Hartree-Fock (TDUHF) iterative procedure has been implemented at the semiempirical level in the MOPAC 2000 package to determine the (non)linear optical responses of open-shell systems. In addition to providing the dynamic quantities, this procedure enables the decomposition of the total (hyper)polarizabilities into their spin contributions. Its application to reference molecules using AMI level is reported to illustrate the capabilities of the method compared to ab initio and experimental results. Although for small systems the semi-empirical scheme fails in reproducing the highly-correlated ab initio values, the TDUHF/AM1 approach appears as an efficient tool for studying larger conjugated systems. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：130 / 135

页数：6

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