Fragmentation of peroxyhemiacetals. Stereoselective synthesis of 1,2-dioxolanes

被引：11

作者：

Hernandez, R

Velazquez, SM

Suarez, E

Prange, T

机构：

[1] CSIC,INST PROD NAT & AGROBIOL,LA LAGUNA 38206,TENERIFE,SPAIN

[2] UNIV PARIS 11,LURE,F-91405 ORSAY,FRANCE

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 35期

关键词：

D O I：

10.1016/0040-4039(96)01360-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new and efficient approach to the synthesis of 1,2-dioxolanes by beta-fragmentation of alkoxy radicals from readily available peroxyhemiacetals, under mild conditions, is described. The radical reaction proceeds in a diastereoselective manner providing a sale 1,2-dioxolane. Copyright (C) 1996 Elsevier Science Ltd

引用

收藏

页码：6409 / 6412

页数：4

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