Electrochromism in diffractive conducting polymer gratings

被引：20

作者：

Admassie, S ^{[1
]}

Inganäs, O

机构：

[1] Linkoping Univ, Dept Phys & Measurement Technol, SE-58183 Linkoping, Sweden

[2] Univ Addis Ababa, Dept Chem, Addis Ababa, Ethiopia

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2004年 / 151卷 / 06期

关键词：

D O I：

10.1149/1.1738676

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The electrochromic polymer poly(3,4-ethylenedioxythiophene)-poly(styrene sulfonate) (PEDOT-PSS) spin-coated on ITO/glass was patterned with a soft lithographic method in order to diffract the incident light and thereby modify absorption of light by the film to improve the electrochromic efficiency of the polymer. The absorbance peak at around 610 nm was found to be much higher in the patterned PEDOT-PSS film than the one observed in the unpatterned film. Values of coloration efficiencies varying from 107 to 174 cm(2)/C were obtained for three different unpatterned PEDOT-PSS films, whereas for three different patterned PEDOT-PSS films higher values ranging from 211 to 371 cm(2)/C were found. These increased values of the electrochromic efficiencies are attributed to diffraction. (C) 2004 The Electrochemical Society.

引用

页码：H153 / H157

页数：5

共 34 条

[1]

Andersson P, 2002, ADV MATER, V14, P1460, DOI 10.1002/1521-4095(20021016)14:20<1460::AID-ADMA1460>3.0.CO

[2]

2-S

[3] MICROSTRUCTURED PHOTOPOLYMER FILMS OF A RUTHENIUM(II) POLYPYRIDINE COMPLEX - FABRICATION OF AN ELECTROCHEMICALLY SWITCHABLE PHASE GRATING [J].

BERGSTEDT, TS ;

HAUSER, BT ;

SCHANZE, KS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (18) :8380-8381

[4] Electrochromic properties of laminate devices fabricated from polyaniline, poly(ethylenedioxythiophene), and poly(N-methylpyrrole) [J].

Boehme, JL ;

Mudigonda, DSK ;

Ferraris, JP .

CHEMISTRY OF MATERIALS, 2001, 13 (12) :4469-4472

[5] All-additive fabrication of inorganic logic elements by liquid embossing [J].

Bulthaup, CA ;

Wilhelm, EJ ;

Hubert, BN ;

Ridley, BA ;

Jacobson, JM .

APPLIED PHYSICS LETTERS, 2001, 79 (10) :1525-1527

[6]

CARLBERG C, 1996, THESIS U LINKOPING S

[7] Electrochemically modulated diffraction - A novel strategy for the determination of conduction-band-edge energies for nanocrystalline thin-film semiconductor electrodes [J].

Dang, XJ ;

Massari, AM ;

Hupp, JT .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2000, 3 (12) :555-558

[8] All polymeric solid state electrochromic devices [J].

De Paoli, MA ;

Casalbore-Miceli, G ;

Girotto, EM ;

Gazotti, WA .

ELECTROCHIMICA ACTA, 1999, 44 (18) :2983-2991

[9] Composite coloration efficiency measurements of electrochromic polymers based on 3,4-alkylenedioxythiophenes [J].

Gaupp, CL ;

Welsh, DM ;

Rauh, RD ;

Reynolds, JR .

CHEMISTRY OF MATERIALS, 2002, 14 (09) :3964-3970

[10] Conductive polymer blends as electrochromic materials [J].

Gazotti, WA ;

Casalbore-Miceli, G ;

Mitzakoff, S ;

Geri, A ;

Gallazzi, MC ;

De Paoli, MA .

ELECTROCHIMICA ACTA, 1999, 44 (12) :1965-1971

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