Stereoselective synthesis of a terpyrrolidine unit, a potential building block for anion recognition

被引：21

作者：

Arndt, HD ^{[1
]}

Polborn, K ^{[1
]}

Koert, U ^{[1
]}

机构：

[1] UNIV MUNICH,INST ORGAN CHEM,D-80333 MUNICH,GERMANY

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 22期

关键词：

D O I：

10.1016/S0040-4039(97)00845-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first stereoselective synthesis of a trans-threo-trans-threo-trans terpyrrolidine was achieved. A bidirectional strategy involving double acetylide coupling of two trans-N-BOC-pyrrolidine-aldehydes 3, epimerisation-free hydrogenation and ring closure via a seven-membered cyclic sulfate gives access to the terpyrrolidine scaffold. (C) 1997 Elsevier Science Ltd.

引用

页码：3879 / 3882

页数：4

共 33 条

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