Alkaline-earth metal compounds as alcoholysis catalysts for ester oils synthesis

被引：108

作者：

Gryglewicz, S ^{[1
]}

机构：

[1] Wroclaw Tech Univ, Inst Chem & Technol Petr & Coal, PL-30344 Wroclaw, Poland

来源：

APPLIED CATALYSIS A-GENERAL | 2000年 / 192卷 / 01期

关键词：

transesterification; ester oil; alkaline catalyst;

D O I：

10.1016/S0926-860X(99)00337-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Some esters of carboxylic acids and polyhydric alcohols are environmental friendly lubricants of superior propel-ties. This work presents an attempt to use alkaline-earth metal compounds as catalysts for alcoholysis reaction in terms of synthesis di(2-ethylhexyl) adipate and an oligomeric ester of neopentyl glycol. Magnesium methoxide, calcium oxide, calcium alkoxides and barium hydroxide appear to be active catalysts for transesterification. The mechanism of catalytic activity of these compounds in alcoholysis reaction has been proposed. Synthesised esters possess suitable physicochemical properties as lubricant oils. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：23 / 28

页数：6