Fabrication and characterization of a porous carbon electrode for desalination of brackish water

被引:54
作者
Lim, Jung-Ae [1 ]
Park, Nam-Soo [1 ]
Park, Jin-Soo [2 ]
Choi, Jae-Hwan [1 ]
机构
[1] Kongju Natl Univ, Dept Chem Engn, Kong Ju 314701, Chungnam, South Korea
[2] KIER, Fuel Cell Res Ctr, Strateg Technol Res Div, Taejon 305304, South Korea
关键词
Electrical double layer; Electrosorption; Desalination; Porous carbon electrode; Wet phase inversion;
D O I
10.1016/j.desal.2008.01.033
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
To increase the surface area of electrodes for electrosorption, porous carbon electrodes were fabricated using a wet phase inversion method. A carbon slurry consisting of a mixture of activated carbon powder (ACP) and polyvinylidene fluoride Solution was cast directly on a graphite sheet. The cast film was then immersed ill pure water for phase inversion. Scanning electron microscopy images verified that the electrodes were porous and the pore size was less than 100 nm. The electrochemical properties were characterized using cyclic voltammetry. The electrical capacitance ranged from 2.18 to 4.77 F/cm(2) depending on the ACP content, and the electrical capacitance increased as the solvent content decreased. The solvent content was an important variable controlling the pore size and capacitance of the electrodes.
引用
收藏
页码:37 / 42
页数:6
相关论文
共 6 条
[1]   Electrochemical enhancement of adsorption capacity of activated carbon fibers and their surface physicochemical characterizations [J].
Han, Yanhe ;
Quan, Xie ;
Chen, Shuo ;
Wang, Shibo ;
Zhang, Yaobin .
ELECTROCHIMICA ACTA, 2007, 52 (09) :3075-3081
[2]   Nanoporous activated carbon cloth for capacitive deionization of aqueous solution [J].
Oh, Han-Jun ;
Lee, Jong-Ho ;
Ahn, Hong-Joo ;
Jeong, Yongsoo ;
Kim, Young-Jig ;
Chi, Choong-Soo .
THIN SOLID FILMS, 2006, 515 (01) :220-225
[3]   Development of a carbon sheet electrode for electrosorption desalination [J].
Park, Kwang-Kyu ;
Lee, Jae-Bong ;
Park, Pill-Yang ;
Yoon, Seok-Won ;
Moon, Jeon-Soo ;
Eum, Hee-Moon ;
Lee, Chi-Woo .
DESALINATION, 2007, 206 (1-3) :86-91
[4]   Activated carbon fiber cloths as electrodes for high performance electric double layer capacitors [J].
Xu, Bin ;
Wu, Feng ;
Chen, Shi ;
Zhang, Cunzhong ;
Cao, Gaoping ;
Yang, Yusheng .
ELECTROCHIMICA ACTA, 2007, 52 (13) :4595-4598
[5]   Electrosorption capacitance of nanostructured carbon aerogel obtained by cyclic voltammetry [J].
Yang, KL ;
Yiacoumi, S ;
Tsouris, C .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2003, 540 :159-167
[6]   Overview of Desalination Techniques [J].
Younos, Tamim ;
Tulou, Kimberly .
JOURNAL OF CONTEMPORARY WATER RESEARCH & EDUCATION, 2005, 132 (01) :3-10