Nanoscale oxides as destructive sorbents for halogenated hydrocarbons

被引：5

作者：

Volodin, Alexander M. ^{[1
]}

Bedilo, Alexander F. ^{[1
]}

Heroux, David S. ^{[2
]}

Zaikovskii, Vladimir I. ^{[1
]}

Mishakov, Ilya V. ^{[1
]}

Chesnokov, Vladimir V. ^{[1
]}

Klabunde, Kenneth J. ^{[3
]}

机构：

[1] Boreskov Inst Catalysis, Novosibirsk 630090, Russia

[2] Univ Maine, Dept Nat Sci, Farmington, ME USA

[3] Kansas State Univ, Dept Chem, Manhattan, KS USA

来源：

SURFACE CHEMISTRY IN BIOMEDICAL AND ENVIRONMENTAL SCIENCE | 2006年 / 228卷

关键词：

nanocrystalline oxides; aerogels; destructive sorbents; halocarbons; MgO; TiO2; titanium oxydifluoride; carbon coating;

D O I：

10.1007/1-4020-4741-X_36

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 [物理化学]; 081704 [应用化学];

摘要：

Destructive adsorption of halocarbons oil nanocrystal line oxides has been studied. The effect of nanoparticle size and phase composition on the reaction kinetics is discussed. The reactivity of nanocrystalline oxides has been found to increase after deposition of a permeable carbon coating. The possibility of synthesis of new nanocrystalline halogenated materials using nanoscale oxides as precursors has been demonstrated.

引用

页码：403 / +

页数：2

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