The development of cryoprobe nuclear magnetic resonance spectroscopy for the rapid detection of organic contaminants in potable water

被引:15
作者
Charlton, Adrian J. [1 ]
Donarski, James A.
Jones, Stephen A.
May, Barry D.
Thompson, K. Clive
机构
[1] Dept Environm Food & Rural Affairs, Cent Sci Lab, York YO41 1LZ, N Yorkshire, England
[2] ALcontrol Labs, Rotherham S60 1BZ, S Yorkshire, England
来源
JOURNAL OF ENVIRONMENTAL MONITORING | 2006年 / 8卷 / 11期
关键词
D O I
10.1039/b611760k
中图分类号
O65 [分析化学];
学科分类号
070302 [分析化学]; 081704 [应用化学];
摘要
The detection of trace levels of a range of organic contaminants ( including pesticides, toxins and an explosive) in potable water, using cryoprobe NMR spectroscopy with limited sample preparation and rapid acquisition times, is described. Emphasis is placed on the applicability of NMR spectroscopy for use in emergency scenarios as the unbiased nature of the technique facilitates the detection and characterization of unknown compounds at levels as low as 50 mu g L(-1).
引用
收藏
页码:1106 / 1110
页数:5
相关论文
共 10 条
[1]
Increase in signal-to-noise ratio of >10,000 times in liquid-state NMR [J].
Ardenkjaer-Larsen, JH ;
Fridlund, B ;
Gram, A ;
Hansson, G ;
Hansson, L ;
Lerche, MH ;
Servin, R ;
Thaning, M ;
Golman, K .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2003, 100 (18) :10158-10163
[2]
Performance of the ultra wide bore 900 MHz NMR magnet at the national high magnetic field laboratory [J].
Dixon, LR ;
Markiewicz, WD ;
Brey, WW ;
Shetty, KK .
IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY, 2005, 15 (02) :1334-1337
[3]
Losonczi J, 2004, AM LAB, V36, P26
[4]
May B, 2006, ROY SOC CH, P229
[5]
Field and laboratory analysis for detection of unknown deliberately released contaminants [J].
O'Neill, G ;
Ridsdale, C ;
Thompson, KC ;
Wadhia, K .
WATER CONTAMINATION EMERGENCIES: CAN WE COPE?, 2004, (293) :100-109
[6]
OVERHAUSER AW, 1953, PHYS REV, V92, P411, DOI 10.1103/PhysRev.92.411
[7]
Choosing the best pulse sequences, acquisition parameters, postacquisition processing strategies, and probes for natural product structure elucidation by NMR spectroscopy [J].
Reynolds, WF ;
Enríquez, RG .
JOURNAL OF NATURAL PRODUCTS, 2002, 65 (02) :221-244
[8]
SELECTIVE-POPULATION TRANSFER EFFECTS IN NUCLEAR OVERHAUSER EXPERIMENTS [J].
SHAKA, AJ ;
BAUER, C ;
FREEMAN, R .
JOURNAL OF MAGNETIC RESONANCE, 1984, 60 (03) :479-485
[9]
Analysis methods for water pollution emergency incidents [J].
Thompson, K. C. ;
Scott, S. .
Water Contamination Emergencies: Enhancing Our Response, 2006, (302) :216-228
[10]
Generating highly polarized nuclear spins in solution using dynamic nuclear polarization [J].
Wolber, J ;
Ellner, F ;
Fridlund, B ;
Gram, A ;
Jóhannesson, H ;
Hansson, G ;
Hansson, LH ;
Lerche, MH ;
Månsson, S ;
Servin, R ;
Thaning, M ;
Golman, K ;
Ardenkjær-Larsen, JH .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT, 2004, 526 (1-2) :173-181