Autocatalysis and self-inhibition:: Coupled kinetic phenomena in the chlorite-tetrathionate reaction

被引：36

作者：

Horváth, AK

Nagypál, I

Peintler, G

Epstein, IR

机构：

[1] Univ Szeged, Dept Phys Chem, H-6701 Szeged, Hungary

[2] Brandeis Univ, Dept Chem, Waltham, MA 02454 USA

[3] Brandeis Univ, Volen Ctr Complex Syst, Waltham, MA 02454 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 20期

关键词：

D O I：

10.1021/ja048982l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The initial rate of formation of chlorine dioxide in the chlorite-tetrathionate reaction changes in an unusual fashion. The formal kinetic order of both reactants varies over a very wide range. Moreover, chlorite ion behaves not just as a simple reactant, but also as a self-inhibitor. A five-step scheme, derived from an eight-step mechanism, is proposed in which the autocatalytic formation of HOCl plays a central role in accounting for this kinetic behavior. Copyright © 2003 American Chemical Society.

引用

页码：6246 / 6247

页数：2

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