A substitution reaction in an oil-in-water microemulsion catalyzed by a phase transfer catalyst

被引：31

作者：

Häger, M

Holmberg, K ^{[1
]}

机构：

[1] Chalmers Univ Technol, Dept Appl Surface Chem, SE-41296 Gothenburg, Sweden

[2] Inst Surface Chem, SE-11486 Stockholm, Sweden

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 08期

关键词：

phase transfer catalysis; phase transfer agent; microemulsion; two-phase system; surfactant; ring-opening reaction;

D O I：

10.1016/S0040-4039(99)02261-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A lipophilic epoxide was reacted with sodium sulfite in a microemulsion using a phase transfer agent as reaction promoter. The microemulsion was based on an aqueous buffer, a chlorinated hydrocarbon and alkyl glycoside surfactants. The reaction was fast compared to the same reaction performed in a two-phase system with the same phase transfer agent. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：1245 / 1248

页数：4

共 6 条

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[2]

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[6]

Starks C.M., 1994, Phase-Transfer Catalysis: Fundamentals, Applications, and Industrial Perspectives

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