A systematic spectroelectrochemical investigation of alkyl-substituted anilines and their polymers

被引：33

作者：

Probst, M ^{[1
]}

Holze, R ^{[1
]}

机构：

[1] TECH UNIV CHEMNITZ ZWICKAU,INST CHEM,D-09107 CHEMNITZ,GERMANY

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 1997年 / 198卷 / 05期

关键词：

D O I：

10.1002/macp.1997.021980515

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Various aniline derivatives carrying one or two alkyl substituents in Various positions (alkylanilines, toluidines and xylidines) were polymerized electrochemically. The obtained conducting polymers were characterized by cyclic voltammetry, in situ infrared spectroscopy and in situ conductivity measurements. Differences in the electrochemical properties of the investigated monomers and polymers are explained an the basis of steric and electronic effects of the substituents. These conclusions are supported by data of vibrational spectroscopy.

引用

页码：1499 / 1509

页数：11

共 36 条

[1]

*AUT, 1986, ORG, P301

[2]

BEYER H, 1991, LEHRBUCH ORG CHEM, P28

[3]

BRANDL V, IN PRESS BER BUNSENG

[4]

CATTARIN S, 1988, ELECTROCHIM ACTA, V33, P1977

[5] CONDUCTING POLYMER-BASED BIOSENSORS [J].

CONTRACTOR, AQ ;

SURESHKUMAR, TN ;

NARAYANAN, R ;

SUKEERTHI, S ;

LAL, R ;

SRINIVASA, RS .

ELECTROCHIMICA ACTA, 1994, 39 (8-9) :1321-1324

[6]

DAO LH, 1989, SYNTHETIC MET, V29, pE377

[7] STERIC AND ELECTRONIC EFFECTS IN METHYL AND METHOXY SUBSTITUTED POLYANILINES [J].

DAPRANO, G ;

LECLERC, M ;

ZOTTI, G .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1993, 351 (1-2) :145-158

[8] KINETICS AND MECHANISM OF ANODIC ANILINE OXIDATION [J].

DUNSCH, L .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1975, 61 (01) :61-80

[9]

*FIRM ZIPP KESS CO, PROD INF

[10] THE POLYMERIZATION OF ANILINE AND METHYLSUBSTITUTED DERIVATIVES - ELECTROCHEMICAL AND SPECTROSCOPIC INVESTIGATIONS [J].

HOCHFELD, A ;

KESSEL, R ;

SCHULTZE, JW ;

THYSSEN, A .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1988, 92 (11) :1406-1412

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