Emission sources of atmospheric phosphine and simulation of phosphine formation

被引:55
作者
Cao, HF [1 ]
Liu, J
Zhuang, YH
Glindemann, D
机构
[1] Chinese Acad Sci, Ecoenvironm Sci Res Ctr, Beijing 100085, Peoples R China
[2] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada
来源
SCIENCE IN CHINA SERIES B-CHEMISTRY | 2000年 / 43卷 / 02期
基金
中国国家自然科学基金;
关键词
phosphine; atmosphere; soil; sediment; emission source; precursor; anaerobic biological process;
D O I
10.1007/BF03027306
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Preliminary results on the emission sources of atmospheric phosphine and the types of its precursors in the environment are described. Sunlight plays a more important role than oxygen in its degradation. The vertical profile of phosphine levers in ambient air has been measured. Laboratory simulation of phosphine formation under anaerobic conditions shows that addition of chicken manure, bone powder, or lecithin reads to an increment in phosphine emission. Phosphine can also be adsorbed to soil matrix and thus can survive in soil and sediment. Adsorption and light degradation explain the low ambient levels of phosphine.
引用
收藏
页码:162 / 168
页数:7
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