An efficient two-step synthesis of metal-free phthalocyanines using a Zn(II) template

被引:79
作者
Alzeer, Jawad [1 ]
Roth, Phillipe J. C. [1 ]
Luedtke, Nathan W. [1 ]
机构
[1] Univ Zurich, Inst Organ Chem, CH-8057 Zurich, Switzerland
基金
瑞士国家科学基金会;
关键词
PHOTODYNAMIC THERAPY; ORGANIC-BASES; METALLOPHTHALOCYANINES; GUANIDINOGLYCOSIDES; SUBSTITUENTS; CANCER;
D O I
10.1039/b822985f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new family of cationic phthalocyanines containing four guanidinium groups was synthesized in pyridine-HCl at 120 degrees C; under these conditions zinc was removed from both the starting materials and products to reveal a new synthetic route to metal-free phthalocyanines.
引用
收藏
页码:1970 / 1971
页数:2
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