Ultrasound in polymer chemistry: Revival of an established technique

被引:127
作者
Paulusse, Jos M. J. [1 ]
Sijbesma, Rint P. [1 ]
机构
[1] Eindhoven Univ Technol, NL-5600 MB Eindhoven, Netherlands
关键词
block copolymers; mechanochemistry; metal-polymer complexes; radical polymerization; supramolecular structures; ultrasound;
D O I
10.1002/pola.21646
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The history of ultrasound in polymer chemistry Goes back a ton way. Initially, its uses were limited to being an alternative method of initiating radical polymerizations through the decomposition of solvents to form radicals or through the breakage of polymers leading to macroradicals. Recently, the raw power of ultrasound has been focused through the use of weak linkages in polymer chains, which enables the production of well-defined macroradicals and coordinatively unsaturated metal complexes. (c) 2006 Wiley Periodicals, Inc.
引用
收藏
页码:5445 / 5453
页数:9
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