Influence of EGR compounds on the oxidation of an HCCI-diesel surrogate

被引：30

作者：

Anderlohr, J. M. ^{[1
,3
]}

Piperel, A. ^{[1
,2
]}

da Cruz, A. Pires ^{[1
]}

Bounaceur, R. ^{[3
]}

Battin-Leclerc, F. ^{[3
]}

Dagaut, P. ^{[2
]}

Montagne, X. ^{[1
]}

机构：

[1] IFP Energies Nouvelles, F-92852 Rueil Malmaison, France

[2] CNRS 1C, F-45071 Orleans, France

[3] Nancy Univ, Dept Chim Phys React, CNRS, ENSIC, F-54001 Nancy, France

来源：

PROCEEDINGS OF THE COMBUSTION INSTITUTE | 2009年 / 32卷

关键词：

HCCI; EGR; JSR; Kinetic modeling; n-Heptane/toluene blend; CHEMICAL KINETIC DATABASE; COMBUSTION CHEMISTRY; CONTROLLABLE EGR; AUTO-IGNITION; FUELS; NO; EMISSIONS; RADICALS; METHANE; ALKANES;

D O I：

10.1016/j.proci.2008.06.019

中图分类号：

O414.1 [热力学];

学科分类号：

070201 [理论物理];

摘要：

This paper presents an experimental and numerical study of the impact of various additives oil the oxidation of a typical automotive surrogate fuel blend, i.e. n-heptane and toluene. It examines the impact of engine re-cycled exhaust gas compounds on the control of a Homogeneous Charge Compression-Ignition (HCCI) engine. Series of experiments were performed in a highly diluted Jet-Stirred Reactor (JSR) Lit pressures of 1 and 10 atm (1 atm = 101,325 Pa). The chosen thermo-chemical conditions were close to those characteristic of the pre-ignition period in an HCCI engine. The influence of various additives, namely nitric oxide (NO), ethylene (C2H4) and methanol (CH3OH), oil the oxidation of a n-heptane/toluene blend was studied over a wide range of temperatures (550-1100 K), including the zone of the Negative Temperature Coefficient (NTC). A new detailed chemical kinetic reaction mechanism is proposed for the oxidation of the surrogate fuel. It includes reactions of NO, methanol (CH3OH) and ethylene (C2H4) and is used to explain the obtained experimental data. The mechanism is further used to theoretically Study the impact of other Exhaust-Gas-Recirculation (EGR) Compounds on the hydrocarbon oxidation, namely ethane (C2H6), formaldehyde (HCHO) and carbon monoxide (CO). (c) 2009 The Combustion Institute. Published by Elsevier Inc. All rights reserved.

引用

页码：2851 / 2859

页数：9

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